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SiNcY... (15)

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A space shuttle is filled with Neon Gas at 1.00 atm and 290 K. The gas effuses through a pinhole in outer space at such a rate that the pressure drops by 0.30 torr/s .
(a)If the capsule were filled with ammonia at the same temperature and pressure, what would be the rate of pressure drop?
(b)If the capsule were filled with 30.0mol%HELIUM, 20 mol% OXYGEN and 50.0mol% Nitrogen at a total pressure of 1.00 atm and a temperature of 290 K what would be the corresponding rate of pressure drop?

SiNcY...
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U ALREADY KNOW (1954)

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Which of the following statements best describes the spontaneity of a reaction at 25oC for which Ssys is negative and Ssurr is positive?
  1. The reaction will only be spontaneous if the change in free energy for the system is positive.
  2. The reaction will be spontaneous at all temperatures.
  3. The reaction will be spontaneous only if Ssys is greater in magnitude than Ssurr.
  4. The reaction will be spontaneous only if Ssurr is greater in magnitude than Ssys.
  5. The reaction cannot be spontaneous at 25oC.

Ken
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U ALREADY KNOW (1954)

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A sample of He(g) is placed in a 1.0-L flask at 298 K. The sample of He(g) is then heated to 450 K at constant volume. Microscopic "snapshots"  for the He(g) are shown below.
Ssys for this process is:
  1. positive.
  2. negative.
  3. equal to zero.
  4. It is impossible to tell.

Ken
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U ALREADY KNOW (1954)

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  1. For a particular chemical reaction, Ho is positive and So is negative. Which of the following statements about the spontaneity of the reaction under standard conditions is TRUE ?
    1. The reaction will be spontaneous only if the magnitude of Ho is large enough to overcome the unfavorable entropy change.
    2. The reaction will be spontaneous only if the magnitude of So is large enough to overcome the unfavorable enthalpy change.
    3. The reaction will be spontaneous regardless of the magnitudes of Ho and So.
    4. The reaction cannot be spontaneous.
    5. The reaction will be spontaneous only of Go is positive.

Ken
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You built electrochemical cells as shown in the diagram below. The part of the experimental setup that functioned as a salt bridge is the:
  1. voltmeter.
  2. metal anode.
  3. beaker.
  4. metal cathode.
  5. ceramic disk in the crucible.

Ken
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If 10 mL a 1.0 x 10-4 M solution of a strong acid were added to 100 mL each of one solution containing 1.8 x 10-5 M hydrochloric acid and a second solution containing 1.0 M acetic acid (Ka = 1.8 x 10-5) plus 1.0 M sodium acetate, it is expected that the:
  1. pH of both solutions would remain unchanged.
  2. change in pH would be very large in both solutions.
  3. change in pH would be the same in both solutions.
  4. change in pH would be larger in the solution containing acetic acid and sodium acetate.
  5. change in pH would be larger in the HCl solution.

Ken
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Apoorva . (198)

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IIT-2000
 
A hydrogenation reaction is carried out at 500K.If the same rxn is carried out in the presence of a catalyst at the same rate,the temp. reqd is 400K.Calculate the activation energy of the rxn if the catalyst lowers the activation barrier by 20KJ/mol. 

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<TR><TD>


<DIV ALIGN="right">Glitter Graphics</DIV></TD></TR></TABLE>
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What is the relationship between the following two square-planar compounds? The compounds are:
  1. linkage isomers
  2. optical isomers
  3. coordination isomers
  4. geometric isomers
  5. the same

Ken
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The quantity of a gas that will dissolve in a liquid is:
  1. directly proportional to temperature.
  2. directly proportional to pressure.
  3. inversely proportional to pressure.
  4. independent of both temperature and pressure.
  5. none of the above.

Ken
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The vapor pressure of a volatile solute over a solution is:
  1. proportional to the vapor pressure of the pure solute and the mole fraction of solute in the solution.
  2. proportional to the vapor pressure of the pure solute and inversely proportional to the mole fraction of the solute.
  3. inversely proportional to both the vapor pressure of the pure solute and the mole fraction of the solute.
  4. dependent only on the temperature of the solution.
  5. the same for all concentrations of the solute.

Ken
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Acetaminophen is found in some pain relievers. The structure of acetaminophen is shown below.
What is the molecular formula for acetaminophen?
  1. C6H6NO
  2. C7H6NO2
  3. C8H9NO2
  4. C9H11NO2

Ken
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In visible spectroscopy, the wavelength at maximum absorbance (lambdamax) is usually used for a spectrophotometric analysis because:
  1. chemical substances only absorb visible light at a single wavelength, lambdamax.
  2. the change in absorbance per unit change in concentration is largest at this wavelength.
  3. the change in absorbance per unit change in concentration is smallest at this wavelength.
  4. chemical substances absorb visible light equally well at all wavelengths.
  5. None of these.

Ken
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Which one of the following diagrams best illustrates the microscopic representation for the HALF-EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium hydroxide (NaOH)? Note that water molecules are not shown for clarity.

Ken
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kasirajan (416)

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A Currnet of 2 A is passing fr 5.00 h through a molten tin salt deposits 22.2g tin.
wht is the oxdn state of the tin salt ?






[Ans = 2+
]


"your future depends on what u do in present"
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kasirajan (416)

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how many hours will it take to produce 100 lb electrolytic chlorine frm NaCl in a cell tt carries 1000 A ? the anode efficiency fr the chlorine rxn is 85%.




[Ans = 40.3 hrs]

"your future depends on what u do in present"
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Tarun Sharma (395)

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Here is a matrix match problem>>>>
                                                  
Column 1                                             Column2
 
 (a) A(s) = 3B(g) + C(G)                    (p) Kp/Kc  < 1
(b) 2NO2(g) = N2O4(g)                      (q) N2 has no effect
(c) N2H4(g) = N2(g) + 2H2(g)             (r)Shift back on heating
(d)S8 (s) = 8S(g)                               (s)Kp/Kx  >  1
 
(Kx is eq constant in mole fraction)
 
 
 

Tarun Sharma
BITS - PILANI
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Tarun Sharma (395)

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answer is>>>>
a----s,q
b----p,q,r
c----s
d----s,q

Tarun Sharma
BITS - PILANI
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svj 29 (1517)

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whats the diffrence b/w banana bond and bridge bond.....wnt an elaborated ansr.......
sry frndz i dunno hav d soln...kindly hlp me!!!

PROGRESS ISN'T MADE BY EARLY RISERS OR HARD WORKERS, BUT BY LAZY PEOPLE TRYING TO FIND EASIER WAY TO DO THE SAME.....SO BE LAZZZZYY!!!!
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The electron configuration for nickel in the zero oxidation state is [Ar]4s23d8. Which of the following is the correct valence-bond representation of the complex ion, Ni(CN)4-2 ? Note: Unfilled circles represent two paired electrons from nickel and filled circles represent two paired electrons from the cyanide ion.

Ken
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Which one of the following best explains why water is a monodentate ligand?
  1. The oxygen atom in a water molecule only has one lone pair of electrons that it can use to form a coordinate covalent bond to a metal atom.
  2. Each hydrogen atom in a water molecule has only one electron with which to form a coordinate covalent bond to a metal atom.
  3. The oxygen atom in a water molecule has two lone pairs of electrons, but both pairs are used to form a single coordinate covalent bond to a metal atom.
  4. The oxygen atom in a water molecule has two lone pairs of electrons, but the second lone pair is not close enough to a second coordination site to form a coordinate covalent bond.
  5. None of these.

Ken
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